METHOD OF CURING A NON-WOVEN SUBSTRATE

专利摘要:
nonwoven substrate and method of curling a nonwoven substrate the present invention provides a nonwoven substrate comprising a fibrous web defining a surface; and a benefit agent layer, wherein the benefit agent is selected from a composition of additives, an enhancing component and combinations thereof; wherein the beneficial agent is foamed and is bonded to the fibrous weft surface by means of a curling process. the present invention also provides a method of curling a nonwoven substrate comprising the steps of (a) providing a nonwoven substrate; (b) positioning an applicator adjacent to a hot non-permeable drying surface; (c) by means of the applicator, application, on the drying surface, of an aqueous foamed beneficial agent; (d) allowing the foamed benefit agent to form an adhesive film over the drying surface; (e) directly bond the non-woven substrate to the adhesive film positioned on the drying surface; and (f) scraping the bonded non-woven substrate and the adhesive film from the drying surface. additionally, the present invention provides a non-woven substrate comprising an adhesive film of an aqueous foamed benefit agent, wherein the benefit agent is selected from an additive composition selected from a synthetic water-soluble polymer, a polymer soluble in natural water and mixtures thereof; an intensifying component selected from the group consisting of microparticles, thermally expandable microspheres, cut fibers, additional polymer dispersions, fragrances, antibacterials, hydrants, softeners, medicaments and combinations thereof; and mixtures thereof.
公开号:BR112013016334B1
申请号:R112013016334-8
申请日:2011-12-21
公开日:2020-09-01
发明作者:Jian Qin；Deborah J. Calewarts；Jeffrey F. Jurena；Keyur M. Desai；Donald E. Waldroup
申请人:Kimberly-Clark Worldwide, Inc；
IPC主号:

专利说明:

CROSS REFERENCE TO RELATED ORDER
[001] This application claims the benefit of U.S. Patent Application Serial Number 12 / 979,852, filed on December 28, 2010, all of which is incorporated herein by reference. FIELD OF THE INVENTION
[002] The present invention relates to a crimped non-woven substrate comprising a foamed polymer (frothed) and additional softening enhancers and the method of preparing the same. HISTORY OF THE INVENTION
[003] Absorbent non-woven products, such as paper towels, tissue paper, diapers and other similar products are designed to exhibit desired levels of volume, softness and strength. For example, in some tissue paper products, softness is enhanced by a topical additive composition, such as a softening agent, to the outer surface (s) of a tissue paper web. Such additive composition it can be a binding agent, which is applied topically to a substrate, such as a non-woven entity, alone or in combination with crimping operations. Curling can be part of a nonwoven fabrication process, in which tissue paper is adhered to the hot surface of a rotary dryer drum by an additive composition. The tissue paper and additive composition are discarded together from the dryer drum via a scraper blade assembly. The curling adds volume to the base sheets of tissue paper, which in turn increases softness, as determined by hand touch. Other properties are also affected, such as strength, flexibility, crepe folds and the like. Typically, additive compositions can be sprayed onto the dryer drum of a Yankee dryer. However, the spray application process has low levels of chemical mass efficiency (40% to 70%) due to the waste of the additive composition caused by a boundary layer of air close to the dryer surface and relatively high dryer temperatures. Out of necessity, the applicator is typically about 101.6 mm (4 inches) away from the dryer surface. Due to the high speed of rotation of the dryer, the boundary layer of air near the surface of the dryer is pulled along the creation of a pressure barrier, which prevents spray particles from reaching the surface of the dryer.
[004] Furthermore, the modification of any additives, to include additional solid particles and short fibers, which improves the overall softness of a substrate, is somewhat limited. Many additional particles, which can enhance the final hand touch of a substrate, require mixing to form the dispersion, which is sprayed over the dryer. Because many of these particles are larger than spray nozzles, nozzle clogging is an issue that prevents additive dispersion from being properly applied over the dryer surface. Therefore, there is a demand for a method of applying an additive composition alone or in combination with intensified softening particles to a drying surface and, eventually, to a substrate, in order to provide a substrate that has improved smoothness. SUMMARY OF THE INVENTION
[005] The present invention provides a non-woven substrate comprising a fibrous web that defines a surface; and a layer of a benefit agent, the benefit agent being selected from an additive composition, an intensifying component and combinations thereof; the beneficial agent being foamed and bonded to the surface of the fibrous web by means of a curling process.
[006] The present invention also provides a method of curling a nonwoven substrate comprising the steps of (a) providing a nonwoven substrate; (b) positioning an applicator adjacent to a hot non-permeable drying surface; (c) through the applicator, application of an aqueous foamed, beneficial agent to the drying surface; (d) allowing the foamed benefit agent to form an adhesive film over the drying surface; (e) direct connection of the non-woven substrate to the adhesive film positioned on the drying surface; and (f) rejection of the bonded non-woven substrate and adhesive film from the drying surface.
[007] Additionally, the present invention provides a non-woven substrate comprising an adhesive film of an aqueous foamed benefit agent, the benefit agent being selected from a synthetic water-soluble polymer, a natural water-soluble polymer. and mixtures thereof; an intensification component selected from the group consisting of microparticles, thermally expandable microspheres, cut fibers, dispersions of additional polymers, fragrances, antibacterials, moisturizers, softeners, medications and combinations thereof. BRIEF DESCRIPTION OF THE DRAWINGS
[008] For the purpose of illustrating the invention, an example is shown in the drawings, which is exemplary; it being understood, however, that this invention is not limited to the precise dispositions and instrumentalities shown.
[009] Figure 1 is a schematic view of process steps used to create a foam form (froth) according to the present invention.
[0010] Figure 2 is a schematic side view of the Yankee dryer of Figure 1 showing the application of foam to the dryer surface, according to an embodiment of the present invention.
[0011] Figure 3 is a schematic side view of an off-line curling process according to an embodiment of the present invention, showing specifically the application of foam to the surface of a non-porous drum.
[0012] Figure 4 is a schematic view of a tissue manufacturing process using curling equipment.
[0013] Figure 5 is a schematic view of a tissue paper manufacturing process, which does not include curling equipment.
[0014] Figure 6 is a series of SEM photographs showing the structural change of a tissue paper material after being treated by one embodiment of a method of the present invention.
[0015] Figure 7 is a lateral cross section of a parabolic chemical additive applicator.
[0016] Figure 8 is a lateral cross section of a parabolic chemical additive applicator according to an embodiment of the present invention.
[0017] Figure 9 is a front perspective view of the parabolic applicator shown in Figure 8.
[0018] Figure 10 is a front perspective view of the parabolic applicator of Figure 9, modified to include wipes according to another embodiment of the present invention.
[0019] Figure 11 is a partial side perspective view of the parabolic applicator of Figure 10, modified to include end dams according to yet another embodiment of the present invention.
[0020] Figure 12 is a front perspective view of the parabolic applicator of Figure 9, modified to include rollers according to an additional embodiment of the present invention.
[0021] Figure 13 is a partial side elevation of the parabolic applicator in Figure 12.
[0022] Figure 14 illustrates morphological structures of both surface and cross-section of a surface coated with an intensifying component of the present invention.
[0023] Figure 15 shows both a coated film and tissue paper comprising a combination benefit agent of the present invention.
[0024] Figure 16 is a graph plotting GMT x Logits (Log Odds) in relation to the softness of the two-layer tissue paper products comprising a combination benefit agent of the present invention.
[0025] Figure 17 shows a graph plotting GMT x increased caliber of two-layer tissue paper products comprising a combination benefit agent of the present invention. DETAILED DESCRIPTION OF THE INVENTION
[0026] Although the specification concludes with the claims particularly highlighting and distinctly claiming the invention, it is believed that the present invention will be better understood from the following description.
[0027] All percentages, parts and ratios are based on the total weight of the compositions of the present invention, unless otherwise specified. All such weights, as they relate to the ingredients listed, are based on the active level and therefore do not include solvents or by-products that may be included in commercially available materials, unless otherwise specified. The term "weight percentage" can be designated as "weight%" here. Except where specific examples of actual measured values are presented, numerical values, which are referred to here, should be considered to be qualified by the expression “about”.
[0028] As used here, "understanding" means that other steps and other ingredients, which do not affect the final result, can be added. This word encompasses the expressions "consisting of" and "consisting essentially of". The compositions and methods / processes of the present invention may comprise, consist of and consist essentially of the essential elements and limitations of the invention described herein, as well as any of the ingredients, components, steps or limitations, additional or optional, described herein.
[0029] “Composition of additives”, as used here, refers to chemical additives (which are sometimes referred to as chemicals, chemistry, chemical composition and amount of supplement (addon)), which are applied topically to a substrate. Topical applications, according to the method of the present invention, can occur during a drying process, or a conversion process. Additive compositions according to the present invention can be applied to any substrate (for example, tissue paper or non-woven) and can include, but are not limited to polymer dispersions, polymer solutions and mixtures thereof.
[0030] "Air-dispersed weft", as used here, is done with an air forming process, in which bundles of small fibers, with typical lengths ranging from about 3 to about 52 millimeters (mm), are separated and carried in an air supply and then deposited over a formation screen, usually with the aid of a vacuum supply. The randomly deposited fibers are then bonded to each other using, for example, hot air or a spray adhesive. The production of air-dispersed non-woven composites is well defined in the literature and documented in the art. Examples include, but are not limited to, the DanWeb process as described in US Patent No. 4,640,810 to Laursen, et al., And assigned to Scan Web of North America, Inc.; the Kroyer process as described in US Patent No. 4,494 .278 to Kroyer, et al .; and U.S. Patent No. 5,527,171 to Soerensen, assigned to Niro Separation a / s; and the method of U.S. Patent No. 4,375,449 to Appel, et al., assigned to Kimberly Clark Corporation, or other similar methods.
[0031] "Beneficial agents" are compositions or components, which provide benefits to the global treated substrate, such as softness, smoothness, moisture, aromas, and the like. Beneficial agents of the present invention include, but are not limited to "additive compositions" and "enhancing components".
[0032] "Bonded-carded weave" or "BCW" refer to a non-woven weave formed by carding processes, as are known to those skilled in the art and further described, for example, in US Patent No. 4,488,928, to which is hereby incorporated by reference, to the extent that it is consistent with the present invention. In the carding process, a combination of staple fibers, binding fibers, and possibly other binding components, such as an adhesive, can be used. These components are shaped into a bulky ball, which is combed or otherwise treated, to create a substantially uniform weight. This web is heated or otherwise treated to activate any adhesive component, resulting in an integrated lofty material.
[0033] "Coform", as used here, is a meltblown polymeric material, to which fibers or other components can be added. In the most basic sense, cofoim can be made if you have at least one meltblown mold head arranged next to a chute, through which other materials are added to the meltblown materials, as the weft is formed. These "other materials" can be natural fibers, superabsorbent particles, natural polymer fibers (eg, rayon) and / or synthetic polymer fibers (eg, polypropylene or polyester). The fibers can be of discontinuous length. Coform material can contain cellulosic material in an amount of about 10% by weight to about 80% by weight, such as from about 30% by weight to about 70% by weight. For example, in one embodiment, a coform material can be produced containing pulp fibers in an amount of about 40% by weight to about 60% by weight.
[0034] "Curling", as defined here, occurs when a weft, which is adhered to a dryer surface, is removed by scraping with a blade, such as a scraper blade.
[0035] "Enhancing components" of the present invention are beneficial agents, which are additional components, which can be added to the additive composition, in order to confer other tactile or additional benefits, which cannot be achieved by the additive composition alone . The enhancement components include, but are not limited to, microparticles, expandable microspheres, fibers, additional polymer dispersions, flavors, antibacterials, moisturizers, medicaments, softeners, and the like.
[0036] "Foam" (froth), as defined here, is a liquid foam. According to the present invention, when the foaming composition of the present invention is heated on the surface of the dryer, it will not form a solid foam structure. Instead, when applied to a heated surface, the foaming composition converts to a substantially continuous film with air bubbles within the film.
[0037] "Hydro-matted weave", according to the present invention, refers to a weave that has been subjected to columnar jets of a liquid, which cause the fibers to tangle. Hydro-entanglement of a frame typically increases the resistance of the frame. In one aspect, pulp fibers can be hydro-entangled to form a material with continuous filaments, such as a “spunboncT weave. The hydro-matted web, resulting in a non-woven composite, can contain pulp fibers in an amount of about 50% to about 80% by weight, such as in an amount of about 70% by weight. Hydro-matt composite webs, as described above, are commercially available from Kimberly — Clark Corporation, under the name HYDROKNIT®. Hydraulic entanglement is described, for example, in U.S. Patent No. 5,389,202 to Everhart.
[0038] “Nonwoven” is defined here as a class of fabrics in general produced by fixing the fibers together. Non-woven textiles are made by mechanical, chemical, thermal means, with adhesive or solvent, or by any combination thereof. The manufacture of nonwovens is different from weaving, knitting or tufting. Nonwovens can be made from synthetic thermoplastic polymers or from natural polymers, such as cellulose. Tissue-cellulose paper is an example of a non-woven material.
[0039] "Meltblowing", as used here, is a nonwoven weft forming process, which extrudes and strips melted polymer resins with heated, high-speed air to form thin filaments. The filaments are cooled and collected as a weft over a moving canvas. The process is similar to the spunbond process, but the meltblown fibers are much thinner and, in general, measured in micrometers.
[0040] "Processing aids", as used herein, refer to compositions that may assist in the process of forming the treated substrate of the present invention. For example, defoaming agents can serve as suitable processing aids of the present invention. In addition, curling aids can assist with additional adhesion or release properties, for curling the substrate from a drying drum.
[0041] "Spunbond", as used here, is a nonwoven weave process, in which the filaments have been extruded, drawn and dispersed on a moving canvas, to form a weave. The word "spunbond" is often interchanged with “Spunlaid”, but the industry has conveniently adopted the words spunbond or spunbonded to denote a specific weft forming process. This is to differentiate this weft forming process from two other forms of spunlaid weft forming, which are meltblowing and flashspinning.
[0042] “Spunbond / meltblown composite”, as used here, is a laminar composite defined by a multi-layered fabric, which, in general, is made up of several alternating layers of spunbond (“S”) wefts and meltblown (“M”): SMS, SMMS, SSMMS, etc.
[0043] "Tissue paper", as used here, in general, refers to various paper products, such as tissue paper, toilet paper, paper towels, napkins, sanitary napkins, and the like. A tissue paper product of the present invention, in general, can be produced from a cellulosic web having one or multiple layers. For example, in one embodiment, the paper or “cellulosic” product may contain a single layer paper web formed from a combination of fibers. In another embodiment, the paper product may contain a multilayer (i.e., stratified) web. In addition, the paper product can also be a single-layer or multiple-layer product (for example, more than one paper web), one or more of the layers of which can contain a paper web formed according to the present invention.
[0044] The present invention is an alternative to the current method of spraying onto a dryer surface (for example, the drum of a Yankee dryer or a hot calender) of a dispersion or aqueous solution of crisp chemicals. Unlike liquid chemicals, the foamed chemical has sufficient structural integrity to reach the dryer surface against gravity, due to significantly increased viscosity. By creating a foamed chemical according to the present invention, a chemical applicator can be placed in much closer proximity to the dryer surface. In addition, by using the foamed chemical of the present invention, it is feasible to incorporate additional benefits that were otherwise difficult to apply.
[0045] Another advantage of the present invention is that less energy is consumed by the dryer. The close proximity of the chemical applicator to the dryer surface improves the efficiency of the chemical mass (that is, it reduces waste in the application process) and the energy efficiency. Efficiency is increased because the air introduced into the foam of the present invention acts as a thinner. As a result, less heat is required to remove water from the foamed crimp chemical (ie, beneficial agents) during the drying process. This is an improvement over the spray application process, which uses water to dilute the beneficial agent.
[0046] In addition, after the curling step, a layer of the beneficial agent remains on the non-woven substrate surface in order to add more volume and softness. This increase in volume is due to the air trapped inside the coated layer. The intensified softness is due to the beneficial agents, which can be foamed over the dryer surface, and subsequently transferred or adhered to the substrate surface, through the curling process. Although foamed beneficial agents become a film during the drying step, not all of the air trapped in the foam is lost during the drying step due to the higher viscosity associated with higher solids levels in the foamed additive composition.
[0047] Several different substrates of tissue paper can be treated according to the present invention. Examples include, but are not limited to, wet-dispersed weaves, air-dispersed weaves, spunbond weaves, cofoini weaves, carded-bound weaves (BCW), continuous film and hydro-tangled weaves. Typically, the beneficial agent is applied to one side of any substrate, but could be applied to both sides, as desired. Benefit Agents 1. Composition of Additives
[0048] In a desired application, the additive composition can be present at a level of about 50 mg / m2 to about 10,000 mg / m2, or from about 50 mg / m2 to about 1,000 mg / m2, or from about 100 mg / m2 to about 1,000 mg / m2. The difference between these suggested ranges is dependent on whether or not the additive composition is applied to a substrate either on an online machine (such as a tissue paper machine) or on an offline machine (such as a conversion line) non-woven fabric). Additive compositions of the present invention can be in the form of a polymer dispersion or a polymer solution, as shown below. A. Polymer dispersions
[0049] Foamy compositions of water-insoluble polymers can be in the form of dispersions. Water-insoluble polymer materials that are solid, such as powder, granules and the like, can be converted into a foaming dispersion by mixing them with water and surfactant (s), under certain processing conditions, such as pressure extrusion high at an elevated temperature. The polymer dispersion can then be mixed with air and a defoaming agent to convert it to a foam.
[0050] Examples of dispersions according to the present invention include, but are not limited to, a polyolefin dispersion, such as HYPOD 85IOC), commercially available from Dow Chemical, Freeport, Texas, USA; polyisoprene dispersion, such as KRATON®, commercially available from Kraton Polymers U.S. LLC, Houston, Texas, USA; copolymer dispersion in poly (butadiene-isoprene) blocks, such as Butanol®, commercially available from BASF Corporation, Florham Park, New Jersey, USA; latex dispersion, such as E-PLUS®, commercially available from Wacker, Munich, Germany; poly (vinyl-pyrrolidone-styrene) copolymer dispersion and poly (vinyl-ethylene alcohol) dispersion, both are available from Aldrich, Milwaukee, Wisconsin, USA. B. Polymer Solutions
[0051] Foamy compositions of water-soluble polymers can also be in the form of polymer solutions. Water-soluble polymer materials that are solid, such as powder, granules and the like, can be dissolved to form a solution. The polymer solution can then be mixed with air and a defoaming agent to convert it to a foam.
[0052] Examples of polymer solutions according to the present invention include water soluble polymers of both synthetic and polymeric bases. Synthetic water-soluble polymers include, but are not limited to, polyalcohols, polyamines, polyimines, polyamides, poly (carboxylic acids), polyoxides, polyglycols, polyethers, copolymers and mixtures of those listed above.
[0053] Naturally based water-soluble polymers include, but are not limited to modified cellulose, such as cellulose ethers and esters, modified starch, chitosan and its salts, carrageenan, agar, gelan gum, guar gum, others polysaccharides and modified proteins, and combinations thereof. In a particular embodiment, water-soluble polymers also include: poly (acrylic acid) and salts thereof, poly (acrylate esters) and poly (acrylic acid) copolymers. Other suitable water-soluble polymers include polysaccharides of sufficient chain length to form films, such as, but not limited to pullulan and pectin. For example, water-soluble polymers may contain additional monoethylenically unsaturated monomers, which do not carry a pendant acid group, but which are copolymerizable with monomers carrying acid groups. Such compounds include, for example, the monoacrylic esters and monomethacryl esters of poly (ethylene glycol) or poly (propylene glycol), the molar masses (Mn) of the poly (alkylene glycols) being up to about 2,000, for example.
[0054] In another particular model, the water-soluble polymers can be hydroxy-propyl cellulose (HPC) sold by Ashland, Inc., under the trade name KLUCEL®. Water-soluble polymers can be present in the additive composition in any operating quantity and will vary based on the selected chemical component, as well as on the final properties that are desired. For example, in the exemplary case of KLUCEL®, biodegradable water-soluble polymers can be present, in the additive composition, in an amount of about 1% to about 75%, or at least 1% to about 5% , or at least about 10%, or up to about 30%, up to about 50% or up to about 75%, based on the total weight of the additive composition, to provide enhanced benefits. Other examples of suitable water-soluble polymers include methyl cellulose (MC), sold by Ashland, Inc., under the trade name BENECEL®; hydroxy-ethyl-cellulose, sold by Ashland, Inc., under the trade name NATROSOLC and hydroxy-propyl-starch, sold by Chemstar (Minneapolis, Minnesota, USA) under the trade name GLUCOSOL 800®. Any of these chemicals, once diluted with water, are placed on a non-porous, hot dryer surface to finally transfer the chemical to the weft surface. Water-soluble polymers in these chemicals include, but are not limited to, poly (vinyl alcohol), poly (ethylene glycol), poly (ethylene oxide), hydroxy-propyl-starch, hydroxy-propyl-cellulose and combinations thereof.
[0055] Conventional crisp chemicals for tissue papermaking may include water-soluble polymer solutions, such as an aqueous mixture comprising poly (vinyl alcohol) and a polyamide-epialohydrin resin. Although these conventional crisp chemicals comprise water-soluble polymer solutions, they are unable to provide the benefits of the present invention, which include enhanced softness without compromising the strength of the tissue paper sheet.
[0056] The additive composition of the present invention may be commercially available, such as HYPOD 85100 dispersion, from Dow Chemical Company, and consists of water, a poly (ethylene-octene) copolymer and an ethylene and acrylic acid copolymer .
[0057] The poly (ethylene-octene) copolymer can be obtained commercially from Dow Chemical Corporation, under the name AFFINITY® (type 29801) and the ethylene and acrylic acid copolymer can be obtained commercially from Dow Chemical Corporation , under the name PRIMACOR® (type 59081). PRIMACOR® acts as a surfactant to emulsify and stabilize the particles in the AFFINITY® dispersion. The acrylic acid comonomer of PRIMACOR® is neutralized by potassium hydroxide to a degree of neutralization of about 80%. Therefore, in comparison, PRIMACOR® is more hydrophilic than is AFFINITY®. In a dispersion, PRIMACOR® acts as a surfactant or dispersant. Unlike PRIMACOR®, AFFINITY®, when suspended in a dispersion, takes on the form of tiny droplets with a diameter of a few micrometers. The PRIMACOR® molecules surround the droplets of AFFINITY®, to form a “micelle” structure, which stabilizes the droplets. HYPOD 8510® contains about 60% AFFINITY® and 40% PRIMACOR®.
[0058] When the dispersion becomes a molten liquid on the hot surface of the dryer, AFFINITY® forms a continuous phase and PRIMACOR® forms a dispersing phase, which forms islands in the “ocean” of AFFINITY®. This phase change is called a phase inversion. However, the occurrence of this phase inversion depends on external conditions, such as temperature, time, molecular weight of solids and concentration. Finally, phase inversion only occurs when the two polymers (or two polymers) have sufficient relaxation time to allow complete phase inversion. In the present invention, HYPOD 8510® coated film retains a dispersion morphology, which indicates that there is incomplete phase inversion. The benefits of the permanence of the dispersion morphology include, but are not limited to, a more hydrophilic coating layer due to the exposure of the PRIMACOR® phase; and improved smoothness of the coated product due to air bubbles trapped inside the coated HYPOD 8510® layer, which provides extra volume.
[0059] The diluted dispersion may have a very low viscosity (around 0.001 Pa.s (1 cp), just like water). A low viscosity dispersion, when applied over a hot dryer drum, will undergo a water evaporation process and a complete phase inversion of AFFINITY®. The resulting continuous molten film then presents PRIMACOR® dispersion islands embedded in it. The film formed after completely evaporating the water is solid without any air bubbles embedded in it. After the transfer of the molten film over the web by means of the curling process, the thin film covering the surface of the tissue paper is discontinuous even if interconnected, see Fig. 6C discussed above.
[0060] The process of the present invention can use a high viscosity dispersion, high in solids (about 10% to about 30%) and can contain a large amount of air bubbles (the volume of air is at least 10 times more than the dispersion volume). Desirably, the commercially available HYPOD 8510® dispersion (about 42% solids, including both AFFINITY® and PRIMACOR®) has a viscosity of around 0.5 Pa.s (500 cp), while water has a viscosity around 0.001 Pa.s (1 cp). A dispersion containing about 20% HYPOD 8510® can have a viscosity of about 0.2 Pa.s (200 cp), a relatively high viscosity, while a dispersion, having less than about 1% HYPOD 8510® , may have a viscosity closer to that of water (0.001 Pa.s (1 cp)). After trapping a high air ratio, the viscosity of the foamed HYPOD 8510® dispersion increased exponentially, compared to the dispersion before being foamed.
[0061] Referring to Figure 1, when a foamed dispersion is applied over the non-porous dryer surface 23, a limited amount of water will be readily evaporated from it. It is conceived that the slow evaporation of the dispersion, due to the high solids content combined with its high viscosity, will prevent the dispersion of AFFINITY®- PRIMACOR® from completing the phase inversion (in which AFFINITY® becomes continuous and PRIMACOR® becomes a dispersion) and the trapped air escaping. This results in a microstructured molten film on the hot dryer surface.
[0062] Referring to Figure 6, the SEM photos confirm the previous hypotheses. Two immediate benefits can be seen when comparing the surface-treated tissue papers with the surface-treated tissue papers of the present invention. First, the method of the present invention provides tissue paper that is more bulky and has a softer hand feel due to the trapping of air bubbles 21 (see Figure 6b). Second, the tissue paper of the present invention has a more wettable surface, due to the inversion of the incomplete phase, which, in turn, results in exposure of the surface of the hydrophilic component.
[0063] Visually compare FIGS. 6a, 6b, 6c with FIGS. 6a ', 6b', 6c '. The coated layer, showing dispersion beads 19 and trapped air bubbles 21, shown in Figure 6b, is softer than the molten film shown in Figure 6b ', as determined by the Hand Grading Test disclosed here. II. Intensification Components
[0064] The present invention not only provides a substrate with improved softness, due to the beneficial agents and the process described here, but also provides an improved manual touch. Intensifying components are added to the dispersions of the present invention to provide a cottony / fluffy touch to the substrate, rather than the silky / slippery touch, which can often be felt with the use of the dispersions alone. Although the silky / slippery touch may be desirable for some substrates, the present invention provides other options, in order that a variety of textures and aesthetics can be provided. Enhancing components of the present invention include, but are not limited to, microparticles, such as silica gel particles, thermally expandable microspheres, such as EXPANCEL®, fibers, such as cotton linter flakes, polymer dispersions, such as poly (vinyl) -pyrrolidone- styrene), and combinations thereof. When cotton lint flakes or other types of fibers are used, they can be from about 0.1 mm of fiber length to about 5 mm of fiber length.
[0065] In addition to the intensifying components, which provide a contrasting manual touch, the intensifying components can also provide additional benefits, which could not be appreciated with the use of the dispersion alone. Enhancing components of the present invention can also include fragrances, antibacterials, moisturizers, softeners, medicaments and combinations thereof. Such components will provide a global substrate that presents improved touch from dispersion in combination with benefits that cannot have been provided otherwise without the present technology. The present invention can use any or a combination of enhancement components, to be included within the additive composition of the present invention. For example, enhancing components can be added to a dispersion of the present invention in an amount of about 0.5% to about 30%, from about 1% to about 20% or from about 2% to about 10% by weight of the dispersion composition.
[0066] The intensifying components can be added to the foamed chemical before or after the chemical has been foamed. In a desired application, the level of enhancement components is from about 0.5% to about 30%, or from about 1% to about 20%, or from about 2% to about 10% , based on the total dry weight of the additive composition.
[0067] When enhancing components are used in combination with the additive compositions of the present invention, they will provide enhanced softness without compromising strength. For example, when tissue paper is used as the substrate of the present invention, there will be an increase in global log odds (log odds) of about 0.5 to about 18 and a GMT level of about 800 to about 1,200, when compared to substrates that have not been processed in the same way as in the present invention. “GMT”, as used here, refers to the combination of machine directions and machine traverse in determining tensile strength. As shown in Figure 14, morphological structures of both the surface and the cross section are shown in photos A and B. Flax fibers of intensifying component cotton linter are clearly shown on the surface. In photos C and D, the fibers of cotton lint flakes make the tissue paper surface much more "cotton" or "fluffy" than that of HYPOD 8510® alone as the beneficial agent.
[0068] Figure 15 shows both the coated film and tissue paper as a combination benefit agent, where HYPOD 85100 is the additive composition, and expandable microspheres of Expancel® are the intensifying component. It is clearly shown that expanded microspheres remain on the surface of both the film and tissue paper, which will contribute to the improvement of manual touch, when consumers touch them under conditions of use. III. Processing Aids
[0069] Processing aids of the present invention include chemicals that may assist in the process of forming the treated substrate of the present invention. Processing aids may appear slightly or dissipate in the final treated substrate. Although they are included to only assist in the production process of the treated substrates, they can also confer slight benefits to the substrate, which are desired, from the present invention. For the purposes of this application, "processing aids" are those used in the process of defoaming or applying the beneficial agents to the substrate and are not used in the process of preparing the precursor substrate. A. Foaming agents
[0070] Most commercial foaming agents are suitable for creating the foam of the present invention. Suitable foaming agents include, but are not limited to, low molecular weight materials or polymeric materials in liquid form. Defoaming agents can be anionic, cationic or non-ionic. These defoaming agents can be divided into four groups, depending on their function: 1. Air trapping agent - used to enhance the ability of a liquid (dispersion, solution or mixture, etc.) to trap air, which can be measured by determining a “blowing ratio”. An exemplary list of defoaming agents includes, but is not limited to, potassium laurate, sodium laurel sulfate, ammonium laurel sulfate, ammonium stearate, potassium oleate, disodium octadecyl sulfosuccinime, etc. .
[0071] 2. Stabilizing Agent - used to enhance the stability of foam air bubbles in the face of time and temperature; examples include, but are not limited to, sodium laurel sulfate, ammonium stearate, hydroxypropyl cellulose, etc.
[0072] 3. Wetting Agent - used to enhance the wettability of a dried film-coated surface. Examples include, but are not limited to, sodium laurel sulfate, potassium laurate, disodium octadecyl sulfosuccinimate, etc.
[0073] 4. Gelling Agent - used to stabilize air bubbles in the foam, making the additive composition take the form of a gel, which serves to reinforce the cell walls. Examples include, but are not limited to hydroxy-propyl-cellulose, hydroxy-ethyl-cellulose, carboxy-methyl-cellulose and other modified cellulose ethers.
[0074] Some defoaming agents can deliver more than one of the functions listed above. Therefore, it is not necessary to use all four foaming agents in a foaming additive composition. The selection of foaming agents is dependent on the chemistry of the additive composition. For example, when the additive composition comprises an anionic component, such as HYPOD 8510®, suitable foaming agents have to be selected from anionic or non-ionic groups. If a cationic foaming agent is used to enhance the foaming capacity of an anionic additive composition, the cationic components in the foaming agent will form ionic bonds with the anionic components in the additive composition, and will cause both the foaming agent cationic and the composition of anionic additives become insoluble in water, due to the formation of bonds. On the other hand, if an additive composition comprises cationic components, anionic foaming agents are not suitable for use. B. Curling Aid
[0075] Curling aids are chemicals that are added to the benefit agents of the present invention, to optimize the adhesion and release properties of the tissue paper substrate in relation to the dryer surface. These fall largely into the following groups: 1. Adhesion Aid - used to increase the adhesion of the tissue paper sheet to the dryer surface. Examples include, but are not limited to, poly (vinyl alcohol), polyacrylate, hydroxy-propyl-starch, carboxy-methyl-cellulose, chemene, poly (vinyl-amine), copolymers or mixtures thereof.
[0076] 2. Release Aid - used to decrease the adhesion (intensify the release) of the tissue paper sheet (from) the dryer surface. Examples include, but are not limited to, poly (ethylene glycol), poly (propylene glycol), poly (ethylene oxide), poly (propylene oxide), polyolefin, fluorinated polyolefin, copolymer or combinations comprising the above.
[0077] 3. Curing Agent - used to speed up or delay the curing of the curling package, such as a plasticizer or stiffener.
[0078] In general, the preparation of foamed chemicals uses a system that pumps both liquid and air to a mixer. The mixer combines air with liquid to produce a foam, which inherently includes a plurality of small air bubbles. The foam leaves the mixer and drains into an applicator.
[0079] A parameter to define the quality of the foamed chemical is the blowing ratio, which is defined by the volume ratio of small air bubbles trapped by the dispersion chemical in relation to the dispersion volume before mixing. For example, at a blowing ratio of 10: 1, a dispersion flow rate of 1 liter / minute will be able to trap 10 liters / minute of air in your liquid and produce a total foam flow of 11 liters / minute.
[0080] To achieve a high blowing rate, both the mechanical mixing and the foaming capacity of the additive composition are determining factors. If a chemical can only retain or trap air volume up to a blowing ratio of 5, no matter how powerful a foam unit is, it will not be able to produce a stable foam with a blowing ratio of 10. Any extra air in addition to the blowing ratio of 5 it will be released out of the foam system once the mechanical force is removed. In other words, any trapped air higher than the dispersion's air holding capacity will become unstable. Most of such unstable air bubbles will escape the foam (de-bubbling) immediately after the mechanical stirring is stopped.
[0081] Referring to Figure 1, a system 10 is shown schematically, which can generate the foamed chemical according to the present invention. To start, foaming chemicals (for example, HYPOD 8510®, KRATON® and the like) and placed in a chemical tank 12. Chemical tank 12 is connected to a pump 14. It may be desirable to modify piping 13 between the chemical tank 12 and pump 14, so that foaming chemicals can be transmitted to two different pump sizes. Desirably, chemical tank 12 is located at a high level above pump 14, in order to keep the pump under load (primed).
[0082] An optional small secondary pump (not shown) can be used to perform the defoaming process at low speeds with respect to pump 14. The larger primary pump 14 is capable of producing flow rates of up to 25 liters / minute of flow rate. liquid for high application speeds and / or high amount of additive composition. The smaller secondary pump (not shown) is capable of liquid flow rates of up to 500 cm3 / min for low application speeds and / or low additive composition.
[0083] A rheometer 16 is located between the pump (s) 14 and a foam mixer 18. The liquid flow rates are calculated from the desired additive composition, solid chemicals, line speed and applicator width. The flow can vary from about 5: 1 to about 50: 1. When using the small secondary pump, its flow varies from about 10 cm3 / min to about 500 cm3 / min. When using the large pump 14, its flow varies from 0.5 liters / min to about 25 liters / min. A 20 liter / min air rheometer is selected when using the small secondary pump. A 200 liter / min rheometer should be used when operating the larger primary pump 14.
[0084] In one aspect, the foam mixer 18 is used to combine air with the liquid mixture of foaming chemicals, to create small air bubbles in the foam. Air is added metered to system 10 using certain liquid flow rates and blowing ratios, as discussed above. Desirably, foam mixer 18, having a size of 25.4 cm (10 inches) can be used to generate foam. One possible foam mixer 18 is a Foam Generator CSF-10 inch from Gaston Systems, Inc., of Stanley, North Carolina, USA.
[0085] Desirably, the rotation speed of foam mixer 18 is limited to about 600 rpm. The speed of rotation for the mixer in this process is dependent on the ability of the additive composition to foam (that is, its ability to trap air to form stable bubbles). If the additive composition foams easily, in general, a lower rotation speed is required. If the additive composition does not foam easily, a higher rotation speed is generally required. The higher mixer speed helps to accelerate foam balance or optional blowing ratio. The type and / or amount of foaming agent, in addition to the additive composition, also has an effect on the speed requirement of the mixer.
[0086] The foam is checked for uniformity, stability and flow pattern of the bubbles. If uniformity, stability and flow pattern of the bubbles do not conform to the desired standards, adjustments can be made in relation to flow rates, mixing speeds, blowing rate and / or the chemical compositions of solutions / dispersions before targeting the foam to the applicator 24.
[0087] In one aspect of the invention, HYPOD 8510®, or other chemicals to be foamed and used for curling, are combined and added to the chemical tank 12. Diluted HYPOD 8510® solutions (<10% in total solids) and others difficult-to-foam chemicals, in general, require something added to the formulation to increase viscosity and foaming capacity. For example, hydroxypropylcellulose or other foaming or surfactants can be used to produce a stable foam for uniform application over the heated, non-permeable surface of a rotating drum on a dryer surface. Enhancing components, such as silica gel particles or cotton lint flakes, can be added to the additive composition in a number of ways, including, but not limited to: added to the additive composition before the additive composition is pumped into a foaming machine; introduced into the foamed additive composition after the additive composition is leaving the foaming machine, but before the foamed additive composition is applied over the dryer surface; or applied to the dryer before the substrate comes into contact with the additive composition. When the intensifying components are introduced into the additive composition, it is necessary to constantly stir the mixture before adding it to the foaming machine, in order to prevent the solid intensifying component from precipitating at the bottom of the container. When the intensifying components are introduced into the foamed additive composition, a suitable device is required, which ensures uniform mixing of the intensifying components and the foamed additive composition. Substrates
[0088] Suitable substrate materials include, but are not limited to, tissue paper; tissue paper dried using non-curled air (UCTAD); paper towel; HYDROKNIT® non-woven material from Kimberly-Clark Corporation, Neenah, Wisconsin, USA; spunbond; coform; linked-carded frame (“BCW”); film / laminate sheet dispersed by air, and all types of paper, tissue paper and other non-woven products.
[0089] In the non-limiting examples discussed here, the foamed chemical can be applied to a nonwoven, such as tissue paper. As used here, "nonwovens" are intended to include tissue paper, toilet paper, paper towels , spunbond, diaper or linings for female care and external covers, sanitary napkins and the like. Tissue paper can be made in different ways, including, but not limited to, conventionally compressed felt tissue paper; tissue paper intensified with high volume pattern; and high volume non-compacted tissue paper. Tissue paper products from them can be of single or multi-layer construction, such as in U.S. Patent Publication No. 2008/0135195. A modality of a process for forming a wet crimped tissue paper web of the present invention is shown in Figure 4. The additive composition can be applied to the surface of the dryer drum 276 for transfer on one side of the tissue paper web268. In this way, the additive composition adheres the tissue paper web268 to the dryer drum 276. In this modality, as the web 268 is carried through a portion of the rotational trajectory of the dryer surface, heat is given to the web, causing the most of the moisture contained within the web is evaporated. The web 268 is then removed from the dryer drum 276 by a blade 278. The curl of the web 268, as it is later formed, reduces the internal bond within the web and increases the smoothness.
[0090] Another modality for forming a tissue paper of the present invention uses a papermaking technique known as drying through non-curled air ("UCTAD"). Examples of such a technique are described in U.S. Patent No. 5,048,589 to Cook, et al .; in U.S. Patent No. 5,399,412 to Sudall, et al .; in U.S. Patent No. 5,510,001 to Hermans, et al .; in U.S. Patent No. 5,591,309 to Rugowski, et al .; and in U.S. Patent No. 6,017,417 to Wendt, et al. Surface Coating Process
[0091] Unlike a process spraying a dispersion or diluted solution over a dryer surface, such as a Yankee 23 dryer surface (or other suitable dryer drum surface (not shown)), the process of the present invention can apply foamed chemical with a high solids content over the dryer surface 23. In the present invention, air is used to dilute a beneficial agent comprising any level of solids, where the viscosity is within a range that can be pumped by the foaming machine. For example, showing up to about 65% solids, up to about 50% solids, up to about 35%, or up to about 20% solids.
[0092] The high solids coating process of the present invention can exhibit benefits to the product and the process, including, but not limited to, smoother surface due to the unique microstructure of the coated layer (see Figure 6); less chemical waste, due to the intimate and direct application of the foamed chemical; and no need to use softened and deionized water, due to the high chemical to water ratio (for example, a chemical such as HYPOD 8510® becomes unstable when it is exposed to a large amount of hard water, ie , a solids level of 1% or less); and less drying energy needed to dry the foamed chemical as well as the base sheet. Additional benefits, due to the addition of enhancement components, include, but are not limited to, uniformity of the overall benefit agent film coating on the non-woven substrate; enhanced adhesion to the overall benefit agent coating to the non-woven substrate; enhanced mechanical strength of the overall benefit agent coating film; and enhanced stability of the beneficial agent foam from the foam generator unit with respect to the dryer surface.
[0093] Foamed benefit agents can be applied over a substrate 27 in two ways: an online application or an offline application. In the inline processes, a foam generator and an applicator, shown in Figures 1 and 2, will be incorporated into a tissue paper manufacturing line, as shown in Figure 4, and the foamed chemicals will be applied over any substrate 27 during the manufacture of the same. Referring to Figure 3, the offline application makes it possible to apply the foamed chemical to those substrates 80, which are produced by a non-curling process. For example, toilet paper dried using non-crisp air (“UCTAD”) and melt-spun non-woven materials are suitable for use with the offline application method.
[0094] Referring to Figure 1, in one aspect of the invention, the foamed chemicals are applied to the dryer surface 23 via an applicator 24. The foam applicator 24 is positioned close to the dryer surface (0.64 cm or inch) for uniform foam distribution over the dryer surface 23. Such positioning allows better direct contact of the foamed chemical with the dryer surface 23, especially during high speed operations.
[0095] Referring to Figures 2 and 7, it is more desirable to use a single parabolic applicator 24 to apply the chemical to a dryer drum surface 23. However, if varying levels of chemical application are required through width of dryer surface, due to the variability of dryer or base sheet, applicators (not shown), with multiple miniature parabolic applicator zones can be used.
[0096] Referring to Figure 7, a cross section of the parabolic applicator available from Gaston Systems, Inc., located in Stanley, North Carolina, USA, is shown. Preferably, this parabolic applicator 24 has the same length of lip tip (tip) as the width of the substrate. In general, the parabolic applicator 24 features an applicator lip 410 built in part with two steel angle pieces, 412 A and 412 B. These two steel angle pieces define a slit opening 414, through the foamed chemicals can leak. As obtained from the manufacturer, the width 418 of the slot opening 414 is 3.2 mm (1/8 inch), and the edges 416 of the lip tip of steel angle applicator 410 are rounded to eliminate sharp edges.
[0097] Referring to Figures 8 and 9, the complete applicator is shown. Applicator 24 includes a parabolic body 420. From the outside, it can be seen that body 420 is constructed from two plates 422A and 422B, which are joined to and separated by a side member 424. In addition, there is a hose inlet 425, desirably positioned along the symmetrical axis 428 of plate 422 A. The inlet hose 425 can be adjacent to the angle in steel 412A, as seen in Figure 8, or lower, as seen in Figure 9. Generally speaking , the slot width 418 had been narrowed from 3.2 mm (1/8 inch) to about 2.4 mm (3/32 inch). The narrowest slot width 418 increases the speed of the foam towards the desired surface (for example, 23 in Figure 1). In addition, the edges 416 of the lip tip of steel angle applicator 410 are square, not rounded. The square edges 416 increase the surface area of the lip end of applicator 410, which in turn increases the residence time that foamed chemicals have on the lip end of applicator 410. By increasing the residence time, the chemical foam has a greater tendency to stick to the dryer surface 23, as opposed to the downward sliding of the lip end of applicator 410.
[0098] Figure 8 shows that the body inside 420 is a distribution plate 426. The purpose of the distribution plate 426 is to disperse the fluid entering the applicator 24, through the inlet hose 25. The distribution plate has the same general shape as the plates 422, albeit of a smaller size, so that a gap 430 remains between the distribution plate 426 and the side 424. Desirably, the distribution plate 426 is equidistant from each of the plates 422A and 422B. Between the plate 422B and the distribution plate 426, there is a gap, from which fluid can flow into the slot opening 414. Desirably, the slot opening 414 is positioned symmetrically between the plate 422B and the distribution plate 426.
[0099] Referring to Figure 10, in yet another embodiment, the purpose of 440A and 440B felt brushes (referred to collectively as 440 felt brushes) is to spread a substantially uniform thickness of foamed additive composition over the surface dryer 23. This spreading action will result in a film of substantially uniform thickness. Desirably, the felt brushes 440 have approximately the same length as the steel angles 412A and 412B, which define the length of the slit opening 414. This will allow the foamed additive composition to be spread evenly across the dryer surface 23. Note it is noted that the length of the angles in steel 412A, B is greater than the length of the dryer surface, which is aligned with the axis of rotation of the dryer. The distance between the felt brushes 440, between the lip end of the applicator 410 and the outermost edge of the felt brush 446, can be between about 0.2 cm and about 50 cm. Desirably, the 440 rectangular felt brushes are identical in size and shape. The thickness of each brush can vary between 0.125 mm and 25.4 mm, or, desirably, between 3.0 mm and 10 mm. Each of the felt brushes 440 are fixed at a corresponding steel angle 412A and 412B, with a bar clamp 444. Desirably, fasteners such as metal screws (not shown) are spaced along the length of the bar clamp 444 , for fixing to steel angles. Desirably, 440 felt brushes are made from polypropylene and nylon fibers, available from Albany International, located in Homer, New York, USA. However, the felt brush can be made from any other heat-resistant foil materials, such as polymers (i.e., Teflon®), ceramic coated materials, natural-based materials, etc.
[00100] Referring to Figure 11, in one embodiment, applicator 24 is provided with end barriers 450, positioned on each side of the labial end of the applicator. Barrier ends 450 are of identical shape and size, and are used to block the foamed chemical from flowing out in a transverse direction between the 440 felt brushes. Each end barrier is constructed from a material that is not is negatively affected by the heat of the dryer and the chemistry of the additives. Desirably, the end barrier 450 is an almost rectangular block, in which a surface 454 shares the same curvature as the dryer surface 23, and an opposite surface, which has slits from side to side. Slit 452 is T-shaped as defined by the inner surface of the end barrier 450. Specifically, the inner surface of the end barrier 450 is shaped, so that it can slide not only over the steel angles 412A and 412B, but also on bar clamps 444.
[00101] As can be seen in Figure 11, when end barriers 450 are used, the steel angles 412A and 412B are extended beyond the felts 440 to at least the length corresponding to the end barrier length 456. The barrier ends can be held in place by a set of screws. In addition, the barrier ends are positioned against the edge of the felt brushes. Optionally, a metal sheet (shim) (not shown) can be used to contain a flow of foam to the dryer surface and / or to reinforce the felt brushes. Therefore, the metal plate (s) can be positioned close to the felt brush (s) or in place of the felt brush (s).
[00102] Referring now to Figures 12 and 13, in an embodiment of the present invention, rollers 460 are used to minimize the overflow of foam that comes from applicator 24. Rollers 460 include a roll case 462 and a member roll 464. Roll case 462 is an elongated rectangular tube, 466 in width, which fits against the lower arm 470 at an angle in steel 412 (eg 412B) and which is flat ( flush) with the labial tip of the applicator (upper arm 472 from an angle in steel 412). On the uppermost face 480 of each case 462, there is a slot that is dimensioned to allow the roller member 464 to project partially, so that it can be placed in contact with the dryer surface 23. In general, the members 464 rollers are longer than the width of the substrate. When placed against the surface of the dryer 23, the roller member 464 creates a barrier that prevents foam overflow from the applicator 24. The roller member 464, being in contact with the dryer 23, is driven by the rotation speed of the dryer 22.
[00103] Figure 16 Allocates a graph showing GMT vs. logits for softness of a 2-layer tissue paper product using sheets of tissue paper from Table 16, Example 9. The difference in logits between the control code and all foamed and surface treated codes with the benefit agents of this invention is surprisingly large in the vicinity of 18 logits or more. All had higher GMTs than the control code (Code 901), except that the code with both the addition of cotton and the expandable beads (Code 912), which was comparable in strength. The code with particles of silica gel (Code 906) demonstrated a GMT value that is much higher than all codes in a softness parity with the other codes with the benefit agents. This means that this code provides higher softness values at GMT resistance parity, which is one of the benefits of using an intensifying component. The codes with the intensification components (Codes 904-912) also demonstrated a new manual touch in addition to what the softness value in logits can illustrate. In general, the intensifying component causes the additive composition coating (ie, the ocean layer) to exhibit a new and improved manual touch. For example, Code 902 demonstrates the use of HYPOD 8510® as an additive composition and is foamed / surface coated over a substrate without an intensifying component. When its surface is touched, it will provide significant improvement in softness compared to the same tissue paper with conventional crimping chemical (ie Code 901). However, at the same time, it will also have a waxy or slippery feel. Some types of consumers may like that slippery touch, but others may not want to have that touch. The addition of an intensifying component can change the touch without compromising on the smoothness improvement. The manual touch obtained through this approach includes, but is not limited to, cotton, velvety, fluffy and / or hairy. Another benefit of adding the enhancement component (s) is that the HYPOD 8510® coating layer, of additive composition, has improved strength has improved strength, which was important when the benefit agents were applied over pre-prepared substrates, such as thermoplastic fabrics. This improved resistance allows the film coated with the beneficial agents to have a uniform and complete coverage on the substrate.
[00104] Additionally, it has been shown that the intensifying components and the application method could be used to intensify the surface touch, such as softness, or to improve surface properties, such as absorbance, friction, volume, etc. In addition, other surface benefits, such as aromas, antibacterial action, hydration, smoothing agents, etc., could be better applied than the HYPOD 8510® additive composition alone could provide. The code comprising both HYPOD 8510® and poly (vinyl-pyrrolidone-styrene) was perceived to be almost 1.5 logits (significant) softer than the HYPOD 8510® code (Code 902) without any enhancement components.
[00105] The applicants found that the IHR results for the foamed code HYPOD 8510® with 6% silica gel particles, since the intensification components resulted in having the results perceived as the softest with a difference greater than 5 logits of the non-foaming code with conventional crimping chemical. The foamed control of HYPOD 8510® without any enhancement components was close to above a difference of 4 logits. All other foamed codes were perceived to be at least 3 softer logits than the non-foamed control code.
[00106] Another benefit of adding intensification components is the tremendous increase in caliber, which can be achieved while, in general, it is maintained or has greater tensile strength than the code treated on non-foamed surface. These codes were all calendered at the same lamination interval pressure for the facial conversion process. The percentages listed next to the data points are the amounts of the enhancement components added based on the dry weight of HYPOD 8510® in the formulation before defoaming. In Figure 7, all foam and crimped codes showed an additional increase in volume over non-foam and crimped code (Code 901) with the highest level increases by almost 35%. Most codes with the intensifying components have increased in volume compared to the foamed code comprising only HYPOD 8510® (Code 902). All processing conditions, such as blade types, bevel and pressure loads, were the same. Curling Process
[00107] Curling is part of the substrate manufacturing process, in which the substrate is removed by scraping the surface of a rotary dryer (for example, a Yankee dryer) via a blade assembly. Shown in Figure 3 is a simple example of applying a benefit agent being applied as part of an off-the-shelf crimping process. An applicator 109 applies the foamed benefit agent of the present invention to the surface of the surface drum 108. The applicator 109 can be positioned at the bottom of the dryer drum 22. For example, the applicator 109 can be in a “six o'clock” position. , “Twelve o'clock”, “three o'clock” or “nine o'clock”. The lip end of the applicator should be positioned as close to or touching the dryer surface to allow foamed chemicals to contact the dryer surface 23.
[00108] From the tissue roll 85, a woven tissue paper 80 proceeds towards the dryer drum 108 for conversion to a coated tissue paper. A pressing roll 110 provides the pressure necessary to adhere web 85 to the outer surface of dryer 108. The additive composition adheres to the tissue paper web 80 on the surface of dryer drum 108. The additive composition is transferred to the tissue paper web As the weft is curled from the drum using a curling blade 112. Once curled from the drying drum 108, the tissue paper weft80 is wound on a roll 116. EXAMPLES
[00109] The following examples further describe and demonstrate modalities within the scope of the present invention. The examples are given for the purpose of illustration only and should not be interpreted as limitations of the present invention, since many variations of it are possible without departing from the spirit and scope of the invention. Example 1:
[00110] In this example, three dry substrates were used: hydro-matted material with 54 g / m2 (85% cellulose and 15% spunbond), obtainable from Kimberly-Clark Professional®, hydro-matted flannels WYPALL X®-50, paper UCTAD toilet paper with 42 g / m2 and tissue paper with 17 g / m2. (Tissue paper base sheets were not processed until 305 m / min (1,000 fpm)). The dry substrates were treated in an off-line curling process.
[00111] A dispersion of commercial HYPOD 8510® was diluted to a solid level by mill water, which was previously treated by adding Na2COs at a level of 2 g per 10 kg of water, and then foamed by a Gaston CFS 10 inch Foam Generator. In some ways, a foaming agent was used. A defoaming agent is hydroxy-propyl-cellulose, which serves to enhance foam stability. This material may be available from Ashland, Inc., Wilmington, Delaware, USA, and is sold under the brand name KLUCEL®. The stable foam was applied over a hot Yankee dryer surface and then directly bonded to the dry substrate by a pressing roller.
*HYPOD® é uma dispersão aquosa à 42% em peso a partir de Dow e KLUCEL® é hidróxi- propil celulose disponível de Ashland, Inc., com designação K. **Água será adicionada para constituir até 10 Kg de dispersão.[00112] The treated substrate was then removed by scraping the Yankee dryer surface after the foam was cured. Curing should take place at the time defined by the machine speeds listed in Table 1. The Yankee dryer had a diameter of 183 cm (72 inches) and was heated to a surface temperature of around 149 ° C (300 ° F). Table 1 * HYPOD® is a 42% by weight aqueous dispersion from Dow and KLUCEL® is hydroxypropyl cellulose available from Ashland, Inc., with the designation K. ** Water will be added to constitute up to 10 kg of dispersion. Example 2:
(Referindo-se à Tabela 2) Nota: *HYPOD 8510® contém 60% de AFFINITY® e 40% de PRIMACOR®; o produto químico 80/20 contém 80% de AFFINITY® e 20% de PRIMACOR®, com um nível em sólidos de 55% em peso e uma viscosidade em torno de 0,1 Pa.s (100 cp). **KLUCEL® é hidróxi-propil celulose disponível de Ashland, Inc., com designação K. ***Água será adicionada para constituir até 10 Kg de dispersão.[00113] In this group of samples, dry tissueUCTAD paper with a weight of 42 g / m2 was treated in an offline curling process. Coating chemicals were diluted to different levels in solids by mill water, which was previously treated by adding Na ^ CCh at a level of 2 g per 10 kg of water. The dilution was then foamed by the Gastou foam generator. The foam was applied over the Yankee dryer surface (the same dryer as in Example 1) and then attached to the dried UCTAD sheet by a pressing roller. The treated UCTAD sheets were then removed by scraping the Yankee dryer surface and quantities of supplement were cured at a temperature listed in Table 2. Table 2 (Referring to Table 2) Note: * HYPOD 8510® contains 60% AFFINITY® and 40% PRIMACOR®; the chemical 80/20 contains 80% AFFINITY® and 20% PRIMACOR®, with a solids level of 55% by weight and a viscosity around 0.1 Pa.s (100 cp). ** KLUCEL® is hydroxy-propyl cellulose available from Ashland, Inc., with the designation K. *** Water will be added to make up to 10 kg of dispersion. Example 3:
Tabela 3 (Continuação) Nota: *UNIFROTH 0800® é um tensoativo aniônico com um nível em sólidos de 38% disponível de UniChem, Inc.[00114] This is the first example that demonstrates the feasibility of foamed chemical in a tissue paper pilot machine, which operates at a speed that is close to that of a commercial tissue paper machine. Two additives were tested: (1) a crisp chemical made with CREPETROL 870® (90 percent) and CREPETROL 874® (10 percent): it is a liquid with a 25% solids content and available from Ashland, Inc ., located in Wilmington, Delaware, USA; and (2) a commercial polyolefin dispersion, HYPOD 8510®, a dispersion with 42% solids content, available from the Dow Chemical Company. The dispersion had an average particle size of about 1 micrometer, melting point of 63 ° C and a glass transition temperature of -53 ° C. Both chemicals were foamed before being applied over a hot Yankee dryer surface. The dryer has a diameter of 244 cm (96 inches). A defoaming agent, UNIFROTH 0800, a liquid with a solids content of 38%, available from UniChem, Inc., was used to stabilize the foam dispersions of the above two. Table 3 Table 3 (Continued) Note: * UNIFROTH 0800® is an anionic surfactant with a solids level of 38% available from UniChem, Inc. Example 4;
Tabela 4 (Continuação) [00115] In this example, dry substrates were used and treated in an offline curling process. Dispersion of commercial HYPOD 8510® was diluted with mill water to a solids level, which was previously treated by adding NaiCOs, at a level of 2 g per 10 kg of water and then foamed by the Gaston unit, above. The stable foam was applied to the hot drum surface of the 183 cm (72 inch) Yankee dryer and adhered to the dry substrate with a pressing roller. The treated substrates were then scraped off the Yankee surface, after the chemicals were cured during the times and temperatures listed in Table 4. Three dry substrates were used in this example: spunbond and BCW nonwovens, and one UCTAD tissue paper with 42 g / m2. The spunbond is made of a two-component fiber and has a weight of 18 g / m2. BCW has a weight of 20 g / m2. The bicomponent fiber can be a PP / PE (polypropylene / polyethylene) spunbond fiber side by side. See, for example, US Patent No. 5,382,400, incorporated herein to the extent that it does not conflict with the present invention. Table 4 Table 4 (Continued) Example 5:
[00116] In this example, coating chemicals were foamed and applied over the drum of a Yankee dryer in an in-line manner. The dryer had a diameter of 61 cm (24 inches). Using a pressing roller, the film, resulting from applying the amount of foamed supplement to the dryer, was then placed in contact with the wet cellulose pulp sheet, with a consistency of about 40% solids by weight.
[00117] There were four different pulps used in this example. Two pulps were the same as the one used to prepare a Kimberly-Clark tissue paper: Eucalyptus and Pictou fibers (northern softwood kraft), while two other pulps were of comparatively lower cost and quality: Alabama pine fibers Korea (SAP) and recycled SFK, available from SFK Pulp Recycling US, Inc.
[00118] In general, facial tissue paper produced from the lowest cost pulp tends to be less soft. It is desirable to use surface coating with HYPOD 8510® to prepare a low-cost pulp tissue paper, which presents parity of smoothness or even improved smoothness in comparison to a standard tissue paper made with conventional curling chemical.
[00119] The sheet moistened with different combinations of the different pulps was dried on the hot Yankee surface in conjunction with additive chemistry and then removed by scraping the drum surface. Samples 1 to 3 are not coated on the surface with foamed chemicals. Sample 1 was a control tissue paper produced in the same manner as a standard Kimberly-Clark® tissue paper product. Samples 2 and 3 were control samples for low-cost pulp facial tissue papers, which were produced in the same manner as a standard Kimberly-Clark® tissue paper product. All control samples were produced by spraying non-foaming crunch chemicals over the dryer drum. The crisp chemical was prepared by mixing 2,500 mL of 6% poly (vinyl alcohol), 100 mL of KYMENE® at 12.5% and 15 mL of REZOSOL® at 7.5% in 25 gallons of water mill.
Nota: *Água será adicionada para constituir até 10 Kg de dispersão.[00120] For Examples 4 to 9, HYPOD 8510® was diluted to different levels in solids and mixed with additional foaming agent, or KLUCEL® or UNIFROTH 0800®, before each dispersion was foamed by the Gaston foam generator (above) and applied over the dryer, for the treatment of surface coating. Table 5 Note: * Water will be added to make up to 10 kg of dispersion. Example 6:
[00121] In this example, dry substrates were used and treated in an offline curling process. The Yankee dryer had a diameter of 183 cm (72 inches). There were two groups of coating chemicals used in this study: dispersions and solutions. Table 6 summarizes the group of water-soluble solution chemicals and solids levels of mixing solution. For this group, it was necessary to previously dissolve each amount of supplement to form a solution, and then prepare the mixtures from each solution. The commercial HYPOD 8510® dispersion was also diluted to different levels in solids. The prepared solutions and dispersions were foamed by the Gastone foam generating unit applied over the hot dryer drum surface. The resulting film was then placed in contact with the dry substrate by a pressing roller. The treated substrates were then scraped off the Yankee surface, after the chemicals were cured for a while and at the temperatures listed in Table 7. Four dry substrates were used in this group: spunbond with 18 g / m2, toilet paper from UCTAD with 42 g / m2 and tissue paper with 14.1 g / m2.
Tabela 7 Tabela 7 (Continuação) [00122] Table 6 contains information on two types of polymer solutions listed on the left side of the table, and three mixtures of the solutions previously prepared. These three mixtures are R1, R2 and R3. For example, RI is a mixing solution prepared by mixing three previously prepared solutions (45% Glucosol à 10% previously prepared, 40% PEG à 40% previously prepared and 15% Polyox à 2% previously prepared). The mixing solution had a solids level of 20.8%, which is the result of the equation 45% x 10% + 40% x 40% + 15% x 2% = 20.8%. Mixing solids for R2 and R3 are calculated in the same way as for RI. Table 6 Table 7 Table 7 (Continued) Example 7:
[00123] A foam applicator modification was made as described above. All such changes are intended to enhance the vertical velocity of the foam. This will reduce the likelihood that the foam will run off the lip of the applicator and not over the dryer surface. An advantage of such a modification is that it allows the use of a lower flow, to reduce the amount of coating without decreasing the level in solids.
• Pictou é classificado como polpa kraft de madeira macia do norte. • SFK é grau de fibras 100% recicladas disponível de SFK (acima). Tabela 8 (Continuação) [00124] A lower amount of the additive composition can be achieved by reducing the solids levels of HYPOD 8510®. HYPOD 8510® has been diluted to a solids level of 5% or lower, so that lower levels of additive composition are disposed on the tissue paper substrate. However, as mentioned above, the unique microporous structure of the foam is formed largely due to the high viscosity and high solids content of the coating chemicals. The modification of the applicator makes it possible to reduce the levels of composition of additives in tissue paper without compromising the formation of the unique tissue foam structure of the present invention. The samples in Table 8 summarize the operating conditions used with the modified applicator. Codes 1 and 2 were prepared with a conventional curling chemical listed in Example 5. Codes 3-7 were prepared with foamed HYPOD 8510®. Table 8 • Pictou is classified as northern softwood kraft pulp. • SFK is 100% recycled fiber grade available from SFK (above). Table 8 (Continued) Sensory Panel Evaluation Results: Study 1:
[00125] This study was carried out to determine softness using the Hand Classification Test for Tactile Properties (HIR Test). In this study, four tissue paper materials were selected. The following codes were tested from Example 1: UCTAD tissue paper and toilet paper, HYPOD treated tissue paper (Code 10, Table 1) and UCTAD tissue paper (Code 8 , Table 1). Each tissue paper code was a two layer tissue paper or with (1) the coated surface (also the curled side) that faces outwards, so that the user can touch only the softer and smoother side . UCTAD tissue paper with a layer has also been tested, but only has a curled side in accordance with the present invention. The IHR Test only uses the treated side (s).
[00126] Table 9 summarizes the four codes that were the objects of this study. The tissue paper content of HYPOD was determined by measuring the potassium content of tissue paper samples versus the potassium content of dry HYPOD polymer. (The PRIMACOR component of HYPOD is poly (potassium acrylate)). abela 9
[00127] For additional code information, see Table 1.
[00128] Results of Sensory Panel: Two studies of separate sensory panels were conducted: one for the facial tissue paper product of the present invention and the other for UCTAD toilet paper. The softness results are listed in Tables 10 and 11. abela 10
[00129] The results show that the surface treatment of the present invention has perfected the softness of tissuenos paper 2 logits, meaning that it feels like 100 times softer. Both HYPOD-treated facial tissue paper and UCTAD tissue paper performed better than their respective controls with 95% confidence. Study II:
• SFK é grau de fibras 100% recicladas a partir de SFK.[00130] Tissue Paper Product Codes: Six tissue paper materials were selected from Example 5 and converted to 2-layer tissue paper. Both sides of the tissue papers were treated and turned outward. Table 12 summarizes the six codes with HYPOD supplement quantity data. The tissue paper content was determined by measuring the potassium content of the tissue paper samples versus the dry polymer potassium content of HYPOD (The PRIMACOR component of HYPOD is poly (potassium acrylate)). Table 12 • SFK is grade of fibers 100% recycled from SFK.
[00131] The results of the sensory panel are listed in Table 13: Table 13 Example 8:
[00132] In this example, additive compositions were either foamed or diluted before they were applied to the Yankee dryer. The application of the additive compositions was done in line with a foam applicator or with a spray application lance. The foam applicator applied additive chemistry to a Yankee dryer at a solids level of 20% by weight, and the liquid spray application lance (known in the prior art) applied additive chemistry to a Yankee dryer at one level in solids of less than 1% by weight. (The Yankee dryer, in which the film was formed, had a diameter of 61 cm (24 inches)). The chemicals in additives were heated and thus a film structure was formed.
[00133] The wetted sheets were dried on the hot Yankee dryer surface with additive chemistry (now a film), applied to the dryer as a foamed or sprayed HYPOD. Using a pressing roller, the film was directly attached to the dried moistened cellulose pulp sheets containing about 40% solids by weight. (The pulps used for these two codes were eucalyptus and pictou fibers (northern softwood kraft). The tissue paper was then curled by scraping the tissue paper off the dryer surface.
Tabela 14 (Continuação) [00134] Code 1 was the product produced with the spray-applied HYPOD surface treatment. Code 2 was used as a control for current tissuefacial papermaking technology. The amount of additive chemicals applied to tissue papers was about the same for both codes. The additive composition (“coating”) data in Table 14 indicates that they were substantially close, with the spray applied code slightly higher. Both codes were both surface treated by the same additive chemistry, using two different application methods. Any difference in softness between the two codes (according to the IHR Test) is due to the very different structure of the additive composition as applied to the samples. See Figure 6. Table 14 Table 14 (Continued) Study III:
[00135] Tissue Paper Product Codes: Two tissue paper materials were selected from Example 8 and converted to tissue paper products. The resulting tissue tissue paper was then a 2-layer product with the treated side facing outward. Therefore, each surface of tissue papers was treated.
[00136] Results of Sensory Panels: A study of sensory panel was conducted on these two tissuefacial papers. The softness results are listed in Table 15. The results indicate that the facial tissue paper with the foamed HYPOD surface treatment is significantly softer than the tissue paper featuring the spray applied HYPOD surface treatment. Table 15 Example 9:
[00137] In this example, additive compositions and intensifying components were mixed in a container with a powerful stirrer and then diluted to the designated solids level. When the enhancement components were added to the additive compositions, it was important to make sure that the enhancement components dispersed evenly under sufficient agitation. The beneficial agents (additive compositions and mixed enhancement components) were then pumped into a foamed Gastone foam unit before they were applied to the Yankee dryer. The application of the beneficial agent was done in line with a foam applicator. The control code, made with a solution of conventional curling chemicals (refer to Example 5, Code 1) was applied over the Yankee dryer by a spray application lance at a solids level of less than 1% in weight. (The Yankee dryer, in which the film was formed, for each conventional curling chemical solution or benefit agent, had a diameter of 61 cm (24 inches).) Both types of liquids were heated by the dryer and thus , a film structure was formed on the dryer surface.
[00138] The pulps used for these two codes were eucalyptus and pictou fibers (northern softwood kraft with eucalyptus fibers in the outer layers and pictou fibers in the middle layer, as described in Example 5, Code 1). Using a pressing roller, the beneficial agent film (or conventional curling film) was directly bonded to the moistened cellulose pulp sheets containing about 40% solids by weight. The wet pulp sheets were dried on the surface of the hot Yankee dryer, together with the beneficial agents, or with the conventional chemical spray applied chemical. The coated tissue paper was then curled by scraping the tissue paper. dryer surface with a blade.
[00139] Control Code 901 was the product produced with the conventional spray-applied chemical solution solution, while Code 902 was produced with the HYPOD® surface treatment of foamed additive composition of the present invention. However, benefit agents for Code 902 only comprised an additive composition. Codes 904 to 912 were products produced with foamed benefit agents comprising both the composition of additives and the intensifying components. Code 904 had 6% by weight of poly (l-vinyl-pyrrolidone-styrene) dispersion (PVS), available from Aldrich, Milwaukee, Wisconsin, USA as its enhancement component, while Code 905 had 10% by weight of PVS. Code 906 had 6% by weight of solid silica gel (SG) particles with a particle size of 9.5 to 11 micrometers, also available from Aldrich, Milwaukee, Wisconsin, USA and Code 907 had 3% by weight of cotton lint flakes (CLF) with a fiber length of around 0.35 mm, commercially available from International Fiber Corp., North Tanawanda, New York, USA. Code 910 featured 6% by weight of expandable microspheres of Expancel® (EXP) 909 DUX 80, commercially available from AkzoNobel, Duluth, Georgia, USA as its enhancement component, while Code 912 featured two enhancement components: 3% by weight of CLF and 6% by weight of EXP.
Tabela 16 (Continuação) Notas:‘Percentagem de componente de intensificação é calculada com base no peso seco da composição de aditivos; “Produtos químicos de encrespamento de polímero solúvel em água convencionais para produção de papel tissuefacial aplicada por meio de uma lança de aplicação de spray subjacente ao secador Yankee; ‘“Esse GMT foi medido em folha de papel tissue não convertida comparado aos valores de GMT na Figura 12, que foram medidos no produto de papel tissue facial com 2 camadas depois de conversão.[00140] Table 16, below, summarizes the code list, compositions of the beneficial agents used, foaming conditions and detailed production conditions and GMT of the tissue papers produced. Table 16 Table 16 (Continued) Notes: 'Percentage of intensification component is calculated based on the dry weight of the additive composition; “Conventional water-soluble polymer curling chemicals for the production of tissue paper applied using a spray lance under the Yankee dryer; '“This GMT was measured on non-converted tissue paper sheet compared to the GMT values in Figure 12, which were measured on the 2-layer facial tissue paper product after conversion. Example 10:
[00141] In Table 17, 13 different dry substrates were selected and coated on the surface with different beneficial agents with different combinations of additive compositions and intensifying components, to achieve improvement of softness. These substrates are: (1) polypropylene spunbond materials with 8 to 20 g / m2; (2) external cover material for 20 g / m2 disposable training pants; (3) Texol film with 16 g / m2; (4) non-woven material with 24 g / m2 openings; (5) laminated coform / spunbond / coform material with 35 g / m2; (6) 351H Intrepid® filtration media with 68 g / m2, a fabric for air filters at the MERV 8 level; (7) Hydroknit® base sheet with 54 g / m2; (8) diaper cover material with 20 g / m2; (9) SMS material with 12 g / m2; (10) BCW material with 25 g / m2; and (11) coform material with g / m2 comprising 45% Vistamaxx and 55% wood pulp. All dry substrates were treated in an off-line curling process.
[00142] A commercial HYPOD 8510® dispersion or an experimental polyolefin dispersion was mixed separately with different types of intensifying components, in a container, by a powerful stirrer and then diluted to the levels in designated solids. The experimental polyolefin dispersion (DPOD 80/20) is an experimental dispersion provided by Dow Chemical, which comprises a combination of 80% by weight of AFFINITY® and 20% by weight of PRIMACOR®, with a solids level of 55 % by weight, and exhibits a viscosity of about 1.2 Pa.s (1,200 cp). When the enhancement components were added to the additive compositions, it was important to ensure that the enhancement components dispersed evenly under sufficient agitation. The mixed additive compositions and enhancement components (beneficial agents) were then pumped into a foamed Gastone foam unit before they were applied to a hot calender dryer. The application of the benefit agent was done offline with a foam applicator. In the offline application, the beneficial agent foam was applied over the hot surface of the dryer and then directly connected with the dry substrate by a pressing roller. In comparison to the online application, the substrates used are dry and do not contain water. Therefore, the heating capacity requirement for the dryer is much less for the offline application process.
[00143] The treated substrate was then removed by scraping the surface of the hot calender dryer after the foam was cured. The hot calender dryer had a diameter of 49.5 cm (19.5 inches) and was heated to a temperature range between 115 ° C (240 ° F) and 165 ° C (330 ° F), for sufficient curing benefit agents. The selection of the dryer temperature was also related to the type of a substrate material. When the substrate is overheated, it will tend to become rigid and brittle, due to the formation of too many interfiber bonds, which will defy the purpose of this surface treatment.
Tabela 17 (Continuação) [00144] All treated substrates listed in Table 17 exhibited significant improvement in overall softness and manual surface touch compared to their untreated controls. Table 17 Table 17 (Continued) TEST METHODS (1) Hand Classification Test for Tactile Properties (IHR Test):
[00145] In the Hand Classification Test (IHR) it is a basic assessment of hand touch of fibrous wefts and that evaluates attributes, such as softness. This test is useful in obtaining a quick reading as to whether a process change is humanly detectable and / or affects the perception of softness, when compared to a control. The difference in IHR softness data between a treated frame and a control frame reflects the degree of softness improvement.
[00146] A panel of testers has been trained to provide assessments more accurately than an average untrained consumer could provide. The classification data generated for each sample code by the panel were analyzed using a proportional hazard regression model. This model computationally assumes that the panelist proceeds through the classification procedure from more than the attribute being evaluated to at least the attribute. The softness test results are presented as logit values. Logits are the natural logarithm of the risk ratios that are estimated for each code from the proportional hazard regression model. Larger logs indicate that the attribute of interest is perceived with greater intensity.
[00147] Due to the fact that IHR results are expressed in logits, the difference in improved softness is actually much more significant than the data indicates. For example, when the IHR data difference is 1, it will actually represent a 10-fold improvement (101 = 10) in overall softness, or a 1,000% improvement over your control. In another example, if the difference is 0.2, it will represent an improvement of 1.58 times (IO0.2 = 1.58) or 58%.
[00148] Data from IHR can also be presented in a classification format. The data, in general, can be used to make relative comparisons within tests, such as a product classification, and is dependent on the products with which they are classified. Comparisons through the test can be made when at least one product is tested in both tests. (2) Sheet Volume Test
[00149] The leaf volume is calculated as the quotient of the leaf gauge of a conditioned fibrous leaf, expressed in micrometers, divided by the conditioned weight, and expressed in grams per square meter. The resulting sheet volume is expressed in cubic centimeters per gram. More specifically, the sheet gauge is the representative thickness of a single sheet measured in accordance with the TAPPI T402 Test Methods “Standard Conditioning and Testing Atmosphere for Paper, Cardboard, Manual Pulp Sheets and Related Products” and T411 om- 89 “Thickness (caliber) of Paper, Cardboard and Combined Cardboard” with Note 3 for stacked sheets. The micrometer used for the T411 om-89 is an Emveco 200-A Tissue Caliper Tester, available from Emveco, Inc., Newberg, Oregon, USA. The micrometer has a load of 2 kPa, a pressure foot area of 2500 square millimeters, a pressure foot diameter of 56.42 mm, a residence time of 3 seconds and a rate of decrease of 0.8 mm per second. (3) Viscosity Test
[00150] Viscosity measured using a Brookfield Viscometer, model RVDV-II +, available from Brookfield Engineering Laboratories, Midleboro, Massachusetts, USA. Measurements are taken at room temperature (23 ° C), at 100 rpm, or with a spindle of 4 or with a spindle of 6, depending on the expected viscosity. Viscosity measurements are reported in centipoise units. (4) Quantity of HYPOD 8510® Additive Composition Test
[00151] In one aspect of the invention, amount of HYPOD supplement is determined by using acid digestion. Samples are calcined wet with sulfuric and nitric acids sufficient to destroy the carbonaceous material and isolate the potassium ions from the cellulosic matrix. The potassium concentration is then measured by atomic absorption. Supplement amounts of HYPOD 8510® are determined by reference to the potassium concentration of HYPOD 8510® in the sample for apparent HYPOD 8510® measurements from a HYPOD 8510® dispersion solution control (LOTVB1955WC30, 3.53%). (5) Method for Determination of Content in Tissue Paper Additive Composition
[00152] Samples were digested following the EPA Method 3010A. The method consists of digesting a known amount of material with nitric acid in a block digester and bringing it to a known volume at the end of digestion.
[00153] The analysis was performed on an atomic flame absorption spectrophotometer, using the EPA Method 7610 dated July 1986, which is a direct aspiration method using an air / acetylene flame. The instrument used was a VARIAM AA240FS, available from Aligent Technologies, Santa Clara, California, USA.
[00154] The analysis was performed as follows: The instrument was calibrated with a blank and five standards. The calibration was followed by analysis of a second source pattern to confirm the calibration patterns. In this particular case, the recovery was 97% (90-100% being acceptable). Then, a digestion blank and a digestion pattern were analyzed. In this particular case, the blank was less than 0.1 mg / L and the standard recovery was 93% (85-115% being acceptable). The samples were then analyzed and after each tenth sample a standard was processed (90-110% being acceptable). At the end of the entire analysis, a blank and a pattern were processed. (6) Weight
[00155] The weight of the tissue paper specimens was determined using a modified TAPPI T410 procedure. The previously stratified samples were conditioned to 23 ± 1 ° Ceà50 ± 2% relative humidity for a minimum of 4 hours. After conditioning, a stack of 16 previously stratified 7.62 cm x 7.62 cm (3 ”x 3”) samples was cut using a mold press and associated mold. This represents a sample area of sheets of tissue paper 0.0929 m2 or 144 square inches. Examples of suitable mold presses are TMI DGD mold press, manufactured by Testing Machines, Inc., located in Iceland, NY, USA or a Swing Beam testing machine, manufactured by USM Corporation, located in Wilmington, Massachusetts, USA. Mold size tolerances are ± 0.02 cm (0.008 inches) in both directions. The specimen stack is then weighed to the nearest 0.001 grams on a tared analytical balance. The weight in grams per square meter (g / m2) is calculated using the following equation:
[00156] Weight (conditioned) = weight of the pile in grams / (0.0929 m) (7) Average Geometric Tensile Strength (GMT)
[00157] The Average Geometric Tensile Strength (GMT) is the square root of the product of the tensile strength in the dry machine (MD) direction multiplied by the tensile strength in the dry machine transverse (CD) direction, and is expressed as grams 7.62 cm (3 inches) of sample width. The tensile strength in the MD is the peak load per 7.62 cm (3 inches) of sample width, when a sample is pulled to rupture towards the machine. Similarly, the tensile strength in the DC is the peak load per 7.62 cm (3 inches) of sample width, when a sample is pulled to rupture in the direction transverse to the machine. The traction curves are obtained under laboratory conditions of 23.0 ° C ± 1.0 ° C, 50.0 ± 2.0% relative humidity, and after the tissue paper samples have equilibrated to the testing conditions , for a period of not less than four hours.
[00158] The samples for testing tensile strength are cut into strips 76 mm (3 inches) wide by at least 127 mm (5 inches) long in the orientation both in the machine direction (MD) and in the transverse direction machine (CD), using a JDC Precision Cutter (Thwing-Albert Instrument Company, Philadelphia, PA, Model No. SCI30). The tensile tests are measured on an MTS Systems Synergic 100, processed with the TestWorks® 4 version 4.08 computer program (MTS Systems Corp., Eden Prairie, MN, USA).
[00159] The load cell is selected either from a maximum of 50 Newton or from a maximum of 100 Newton, depending on the resistance of the sample being tested, such that most peak load values fall between 10- 90% of the full scale value of the load cell. The measurement length between the jaws is 102 ± 1 mm (4 ± 0.04 inches). The claws are operated using pneumatic action and are coated with rubber. The width of the minimum grip face is 76 mm (3 inches), and the approximate height of a claw is 13 mm (0.5 inches). The crosshead speed is 254 ± 10 mm / min (10 ± 0.4 inches / minute), and the burst sensitivity is adjusted to 65%.
[00160] The sample is placed in the claws of the instrument, centered both vertically and horizontally. The test is then started and ends when the specimen breaks. The peak load is recorded either as the “tensile strength in the MD” or as the “tensile strength in the DC” of the specimen, depending on the direction of the sample being tested. Ten (10) specimens per sample are tested in each direction, with the arithmetic mean being reported as a tensile strength value either on the MD or on the CD for the product. The geometric mean tensile strength is calculated from the following equation: GMT = (Traction on MD x Traction on CD) 1/2
[00161] The dimensions and values described here should not be understood as being strictly limited to the exact numerical values mentioned. Instead, unless otherwise specified, it is intended that each such dimension signifies the mentioned value and a functionally equivalent range surrounding that value. For example, a dimension described as "40 mm" is intended to mean "about 40 mm".
[00162] All documents cited in the Detailed Description of the Invention are, in the relevant part, hereby incorporated by reference; citing any document should not be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a word or phrase in this written document conflicts with any meaning or definition of the word or phrase in a document incorporated by reference, the meaning or definition assigned to the word or phrase in it written document must prevail.
[00163] Although particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made, without departing from the spirit and scope of the invention. Therefore, it is intended to cover, in the attached claims, all such changes and modifications, which are within the scope of this invention.

权利要求:
Claims (6)
[0001]
1. Method of curling a non-woven substrate, characterized by comprising the steps of: (a) providing a non-woven substrate; (b) positioning an applicator adjacent to a non-permeable, hot drying surface; (c) by means of said applicator, applying to the drying surface, an aqueous foamed benefit agent, wherein said benefit agent comprises an additive composition; (d) allowing the foamed benefit agent to form an adhesive film on the drying surface, the adhesive film having air bubbles within it; (e) directly bond the non-woven substrate to the adhesive film positioned on the drying surface; and (f) scraping the bonded non-woven substrate and the adhesive film from the drying surface.
[0002]
Method according to claim 1, characterized in that the additive composition comprises a mixture of a synthetic water-soluble polymer and a natural water-soluble polymer.
[0003]
3. Method according to claim 1, characterized by the fact that the polymer dispersion is selected from the group consisting of polyolefin dispersions, copolymer dispersions in poly (butadiene-styrene) blocks, latex copolymer dispersions pyrrolidone-styrene, poly (vinyl alcohol-styrene) copolymer dispersions and combinations thereof.
[0004]
4. Method according to claim 1, characterized by the fact that the beneficial agent additionally comprises an intensifying component.
[0005]
5. Method, according to claim 4, characterized by the fact that said intensification component is selected from the group consisting of microparticles, thermally expandable microspheres, cut fibers, additional polymer dispersions, fragrances, antibacterials, moisturizers, smoothing agents , drugs, and combinations thereof.
[0006]
6. Method, according to claim 1, characterized by the fact that the non-woven substrate is tissue paper and exhibits increased softness according to the Hand Classification Test for Tactile Properties (HIR Test) of 0.5 logits to 18 and a GMT level of 800 to 1,200.

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法律状态:
2017-02-07| B08F| Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]|

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2017-03-28| B08H| Application fees: decision cancelled [chapter 8.8 patent gazette]|

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2019-07-09| B06T| Formal requirements before examination [chapter 6.20 patent gazette]|

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2020-07-07| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2020-09-01| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/12/2011, OBSERVADAS AS CONDICOES LEGAIS. |

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2020-11-24| B15G| Petition not considered as such [chapter 15.7 patent gazette]|

优先权:

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申请号 | 申请日 | 专利标题

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US12/979,852|2010-12-28|

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US12/979,852|US20120160400A1|2010-12-28|2010-12-28|Method of Indirect Application of Frothed Chemistry to a Substrate|

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US13/330,440|2011-12-19|

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US13/330,440|US8916012B2|2010-12-28|2011-12-19|Method of making substrates comprising frothed benefit agents|

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PCT/IB2011/055865|WO2012090129A2|2010-12-28|2011-12-21|Substrates comprising frothed benefit agents and the method of making the same|BR122019018561-1A| BR122019018561B1|2010-12-28|2011-12-21|NON-WOVEN SUBSTRATE|